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Shelf life of hardener

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john in la

09-27-2004 12:10:37




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I have a can of opened hardener. The can says use in 14 days of opening. It is PPG if that makes a difference.

I read on this forum a few weeks ago that putting it in the fridge would extend the shelf life after opening so that is what I did.

My question is; How do I tell if this hardener is still any good? What does it do when it goes bad? If it is still a liquid is it still good?

I am thinking that hardener goes bad by getting hard in the can after opening. But it may be that the chemical reaction does not work as well after being exposed to air for so long.

For the cost of it I would rather buy some new than ruin my paint job but I am trying to paint pieces parts and it is sometimes a while before I can get back to do another piece.

Thanks for your advise.
John

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Larry806

09-28-2004 07:38:02




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 Re: Shelf life of hardener in reply to john in la, 09-27-2004 12:10:37  
I used some that was over 20 days old a couple years ago on a pickup. In around 9 months tiny bubbles started to show in the paint. PPG factory rep looked at it & said your hardener was to old. He got a microscope out that could see through the paint & showed us. He explained that the hardener turns to a silicone under the paint if it was to old. He told us to keep it in the frig. and throw it away after 10 days. PPG will give us everything to repaint it but that's a lot of work to do over

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Rod (NH)

09-27-2004 19:09:57




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 Re: Shelf life of hardener in reply to john in la, 09-27-2004 12:10:37  
Hi John,

Well, the safe and conservative approach would be to use it up within the 14 days or chuck it. It's always an issue with those of us who do things piecemeal at diffferent times over a long period. The stuff is reasonably expensive so I find it hard to just throw it away. I have used the OMNI MH168 hardener that had been opened and partially used up two years previously and did not have a problem. I am advised that as long as it is not "lumpy" or "cloudy" or other such obvious abnormality that it is probably alright but that is only hearsay from net talk. I can only verify that some small parts I painted last Spring using 2 year old MH168 turned out just fine. You'll have to make the cost/benefit judgment call yourself.

third party image Rod

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CNKS

09-27-2004 12:59:32




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 Re: Shelf life of hardener in reply to john in la, 09-27-2004 12:10:37  
I don't think the 14 days is particularly accurate--it may be just a ballpark figure by PPG. I believe Rod(NH) has used older hardener with good results. It will not harden in the can, as it needs the paint before it sets up. I have been afraid to use old hardener, given the work it takes to prepare for painting. My one experience was on some Farmall lights when month old or so hardener did not seem to cure properly. They look "fair", I have not repainted them. One of them I use as a prop to keep from falling off the tractor when I get off, that probably is why it did not look cured. There is a product called Bloxygen (do a search) that will extend the life, as will refrigeration. I have heard the Mig gas will do the same thing. Just give it a squirt before closing.

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Rod (NH)

09-27-2004 19:18:45




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 Re: Shelf life of hardener in reply to CNKS, 09-27-2004 12:59:32  
CN,

I don't think you would want to use a typical MIG shielding gas - at least that used for steel. That would commonly be a 75/25 mix of argon and CO2 or even straight CO2. It's probably better than just air but my guess is that a fully inert gas would be best, such as straight argon that is generally used in the TIG process, although it is also used in MIG welding of aluminum. I have never tried using argon but will the next time I open a fresh can of hardener. BTW I have some Picklex 20 on order that I will be trying out. I am planning on sandblasting some parts in a blast cabinet this winter but will not be able to prime or paint until warm weather in the Spring. It would appear that Picklex 20 would be the ideal product to use in such a situation.

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CNKS

09-28-2004 08:02:29




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 Re: Shelf life of hardener in reply to Rod (NH), 09-27-2004 19:18:45  
The mig gas thing is something I too read on the internet -- I don't weld so I am not at all familiar with the different gases--I suppose the Bloxygen I use works -- it is really designed to keep the film out of opened paint cans. I'm not a chemist, so I can't comment further. Good luck with the Picklex. It is very easy to use. As far as whether it works or not, I have a 2 year old paint job, that hasn't fallen off yet. I'm still not clear on whether or not it should be used on cast, but I haven't had any problems-yet.

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john in la

09-27-2004 18:24:40




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 Re: Shelf life of hardener in reply to CNKS, 09-27-2004 12:59:32  
Thanks CNKS;
I am like you. To much work to take a chance on might not work correctly.
If their is no way to look at it and tell if it is good or not with out using it then it is trash.
I would rather pay for another can than chance a half a$$ job.



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Frank Stalfire

09-27-2004 20:00:08




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 Re: Shelf life of hardener in reply to john in la, 09-27-2004 18:24:40  
HI John
Although I work for Dupont and you are using PPG we all buy Isocynate from the same supplier, the Bayer corp.what solvent or concentration of Iso's and blends of solvent we use are unique. The thing with Iso's is they crosslink with themselves in the presence of moisture and by solvent evaporation, using the freezer slows solvent evaporation by will not stop the crosslinking with itself from moisture. We, DuPont, only give a 6 month warranty on UNopened cans and want you to use the activator within two weeks after opening. So, all this means exactly what you've been hearing, use it up or replace it.
Frank

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Rod (NH)

09-28-2004 17:52:57




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 Re: Shelf life of hardener in reply to Frank Stalfire, 09-27-2004 20:00:08  
Hi Frank,

Is this something new from DuPont? Their 8105S urethane activator for Centari AE has no indication on the label that I can see. The can I have is about 3 years old so that maybe the reason. There is no indication that the contents should be used within 14 days of first opening and nothing mentioned about any 6 month limit on warranty of "unopened" cans. The only caution that I can find along those lines is that it says to "Keep container of 8105S tightly closed." There is also no indication of time dependent usage constraints in the tech sheet for the Centari Ultra mix that uses that particular activator. How can a part time purchaser of such products tell when any 6 month warranty begins and ends? Are there now date stamps or serial number indicators on the can labels? In my neck of the woods a can of 8105S could very well sit on a retailers shelf for 6 months :o). I realize that DuPont warranties may not apply to DIY users (e.g. "not for use by the general public" labeling) that are not trained and "certified" by DuPont but I am curious as to how things are tracked in the pro shops regarding such time windows.

third party image Rod

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Frank Stalfire

09-28-2004 20:32:35




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 Re: Shelf life of hardener in reply to Rod (NH), 09-28-2004 17:52:57  
Hi Rod
I guess the problem is Nothing Dupont or any of the 3 major paint manufactuers make are intended nor directed to the DIYer and 80% of what we sell is developed for the collission refinish market, the other 20 would be fleet. That in mind the shops and our distribution network, called jobbers, are focused on cycle times and inventory rotations, we make our jobbers responsible for selling the customer "fresh" product. So when I mention we only warrant activator for 6 months that is more of an internal policy that we press our jobbers about, if the jobber decides he will warrant a product longer he is able to do so since the distributers are independently owned and the money would come out of there pocket. Hope that makes sense.

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CNKS

09-28-2004 08:08:33




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 Re: Shelf life of hardener in reply to Frank Stalfire, 09-27-2004 20:00:08  
Frank--Do you think the gas will work? Some people swear by it. I haven't had enough experience with it to have an opinion. I'm not asking for the official DuPont stand, just what you think.



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Frank Stalfire

09-28-2004 11:35:40




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 Re: Shelf life of hardener in reply to CNKS, 09-28-2004 08:08:33  
I also have had no experience with that approach, sounds like it covers the bases, keeps product sealed and dry, I was talking to another Duponter today and asked if he had heard of such a thing, he did not. If I talk to a chemist this week I will ask and let you know what they say. By the way, off the record, I myself have used hardener that was at least 6 months old with no problems, also I know of no long term affect of using expired hardener, the issue is the application, old hardener will make paint look "seedy" in the can and on the surface of the car.

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Big Jim

09-27-2004 23:35:37




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 Re: Shelf life of hardener in reply to Frank Stalfire, 09-27-2004 20:00:08  
The real answer seems to be : It varies. 14 days is going to be a lot different in Miami than in the cool, dry Rockies.
By all means, if you are nervous about it, buy fresh hardener. I will go on adding pure argon to my cans of hardener and sealing out anything that can reach the surface of the hardener. I will store it in a protected area tightly capped. And I'll continue using my 2-year-old hardener without any difficulty. I would bet money that the 14 day / 6 month thing is included on the packaging at the insistance of the lawyers and not the chemists. They don't want any image problems so they take the worst-case senario and cut it in half just to be sure.

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Big Jim

09-27-2004 23:29:44




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 Re: Shelf life of hardener in reply to Frank Stalfire, 09-27-2004 20:00:08  
The real answer seems to be : It varies. 14 days is going to be a lot different in Miami than in the cool, dry Rockies.
By all means, if you are nervous about it, buy fresh hardener. I will go on adding pure argon to my cans of hardener and sealing out anything that can reach the surface of the hardener. I will store it in a protected area tightly capped. And I"ll continue using my 2-year-old hardener without any difficulty. I would bet money that the 14 day / 6 month thing is included on the packaging at the insistance of the lawyers and not the chemists. They don"t want any image problems so they take the worst-case senario and cut it in half just to be sure.

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