I'm not sure if you are referring to 'smoke scum' which is mostly tars and partially burned fatty alcohols; liquid nicotine which is typically a clear liquid; or tobacco spit and spillage.
Smoke scum is tough. Really, without steam cleaning the fabric it is impossible to get out. Stanley Steamer and Serve Pro can treat it the same way they treat a fire damaged house. Works well. Anything else is simply covering the smell.
Liquid nicotine is rather frightening due to its acute toxicity in small quantities. If this is what you are referring to, that's going to take a haz mat approach.
Tobacco spit... good luck. Ive stained carpets with spilled cups, cans, and bottles. I can get the smell out but there are few staining solutions better. Might steam clean it out, the detailing shops cant touch it with anything on the shelf. Its right up there with heavy railroad grease.
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