28% or in some areas it is 32% is liquid N, fairly safe to handle. It is more or less urea that is dissolved into water. It tends to be a little expensive. Works nice for an N boost but price it out if it is your main form of N, you have to handle a lot of gallons when it is only 28% nitrogen.
The nh3 I mentioned below is the pressurized gas. It is often the cheapest form of N, but yes you need to handle it carefully. It seeks water very aggressively, once it catches up with enough water it becomes a very safe and stable thing with no long term concerns at all, but until then it will suck the water right out of you so you do need to be careful with it while applying.
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