It is alcohol based, it will blend with the water, doing 2 things, it prevents solid freeze up, there may still be some ice but it will be porous and slushy enough to still allow some flow. It will also be flammable enough that as the water/alcohol mix is fed into the fire it will still try to burn. It might surge and sputter, but unless it is overwhelmingly water contaminated, it will still try to burn.
It does have its limitations and needs to be in there as a preventive, not an afterthought.
Draining the water off the bottom, eliminating low spots in the line, and spin-on traps that can be removed and replaced while frozen is the first line of defense.
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